Photoinduced absorption spectra of different polycarbazolyldiacetylenes in the visible and infrared regions are reported. Long-lived bipolaronic defects, photogenerated by excitation above the band-gap (2.54 eV), are found responsible for the observed signals. Associated with these defects, photogenerated infrared active vibrations (IRAV) are observed as absorption bands or apparent bleachings arising from Fano-type interference. This different behaviour originates from the different degree of overlap of the IRAV modes with the associated low-energy bipolaronic absorption.
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Titolo: | LONG-LIVED DEFECTS IN POLYCARBAZOLYLDIACETYLENES. PHOTOINDUCED VIS AND INFRARED SPECTRA |
Autori: | |
Data di pubblicazione: | 1994 |
Rivista: | |
Abstract: | Photoinduced absorption spectra of different polycarbazolyldiacetylenes in the visible and infrared regions are reported. Long-lived bipolaronic defects, photogenerated by excitation above the band-gap (2.54 eV), are found responsible for the observed signals. Associated with these defects, photogenerated infrared active vibrations (IRAV) are observed as absorption bands or apparent bleachings arising from Fano-type interference. This different behaviour originates from the different degree of overlap of the IRAV modes with the associated low-energy bipolaronic absorption. |
Handle: | http://hdl.handle.net/11567/303410 |
Appare nelle tipologie: | 01.01 - Articolo su rivista |