Calcium oxides for CO2 capture obtained from the thermal decomposition of CaCO3 particles coprecipitated with Al3+ ions

Calcium-carbonate powders were coprecipitated with Al3+ and then decomposed in air and/or under a CO2 flux between 590 ◦C and 1150 ◦C. The data were analysed using a consecutive-decomposition-dilatometer method and the kinetic results were discussed according to the microstructure analysis done by N2 adsorption isotherms (78 K), SEM and FT-IR measurements. Below 1000 ◦C, CaCO3 particle thermal-decomposition was pseudomorphic, resulting in the formation of a CaO grain porous network. When the CaO grains were formed, the Al3+ diffused among them, producing AlO4 groups that promoted the CaO grain coarsening and reduced O2− surface sites available to CO2 adsorbed molecules to form CO32−.In pure CaO, CO32− diffused through the grain boundary, enhancing Ca2+ and O2− mobility; AlO4 groups reduced CO32− penetration and CaOsintering rate. Above 1000 ◦C, the sintering rate of the doped samples exceeded that of the undoped, likely because of Al3+ diffusion in CaO and viscous flow.