Long-range dispersion and induction coefficients for the homodimers of Li-2, Na-2, K-2 are evaluated in the LALBM scheme using explicit formulae presented previously and numerical values of moments, polarizabilities and dispersion constants obtained from 2-term reduced spectra of the Kaiserslautern group. While induction coefficients are 5-8 times smaller than dispersion, induction anisotropies are always larger than the corresponding dispersion anisotropies for all homodimers.
Long-range dispersion and induction coefficients for the homodimers of Li2, Na2 and K2
MAGNASCO, VALERIO;OTTONELLI, MASSIMO;FIGARI, GIUSEPPE;RUI, MARINA;COSTA, CAMILLA
1999-01-01
Abstract
Long-range dispersion and induction coefficients for the homodimers of Li-2, Na-2, K-2 are evaluated in the LALBM scheme using explicit formulae presented previously and numerical values of moments, polarizabilities and dispersion constants obtained from 2-term reduced spectra of the Kaiserslautern group. While induction coefficients are 5-8 times smaller than dispersion, induction anisotropies are always larger than the corresponding dispersion anisotropies for all homodimers.
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