The C8 and C10 long-range induction coefficients for two like centrosymmetric linear molecules are derived explicitly using the irreducible properties of spherical tensor operators. An application to the H2-H2 system shows that whereas the isotropic induction coefficients are 50-100 times smaller than dispersion, the induction anisotropies γn are always larger than the corresponding dispersion anisotropies.
Long-range induction coefficients for like centrosymmetric linear molecules and an application to H2-H2
MAGNASCO, VALERIO;OTTONELLI, MASSIMO;RUI, MARINA;COSTA, CAMILLA
1998-01-01
Abstract
The C8 and C10 long-range induction coefficients for two like centrosymmetric linear molecules are derived explicitly using the irreducible properties of spherical tensor operators. An application to the H2-H2 system shows that whereas the isotropic induction coefficients are 50-100 times smaller than dispersion, the induction anisotropies γn are always larger than the corresponding dispersion anisotropies.File in questo prodotto:
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