Efficient Near‐Infrared Light‐Emitting Diodes Based on CdHgSe Nanoplatelets

Cadmium mercury selenide (CdHgSe) nanocrystals exhibit a unique combination of low-energy optical absorption and emission, which can be tuned from the visible to the infrared range through both quantum confinement and adjustment of their composition. Owing to this advantage, such nanocrystals have been studied as a promising narrow-band infrared light emitter. However, the electroluminescence of CdHgSe-based nanocrystals has remained largely unexplored, despite their potential for emitting light in the telecom wavelength range. Further benefits to their optical properties are expected from their shape control, in particular the formation of 2D nanocrystals, as well as from a proper design of their heterostructures. In this work, a colloidal synthesis of CdHgSe/ZnCdS core/shell nanoplatelets (NPLs) starting from CdSe template NPLs employing a cation exchange strategy is developed. The heterostructures synthesized exhibit photoluminescence that can be tuned from approximate to 1300 to 1500 nm. These near-infrared-active NPLs are employed in light-emitting diodes, demonstrating low turn-on voltage and high external quantum efficiency.A colloidal synthesis of CdHgSe/ZnCdS core/shell nanoplatelets (NPLs) starting from CdSe template NPLs employing a cation exchange strategy is developed. The heterostructures synthesized exhibit photoluminescence which can be tuned from approximate to 1300 to 1500 nm. These near-infrared-active NPLs are employed in light-emitting diodes, demonstrating low turn-on voltage and high external quantum efficiency.image