A novel synthetic strategy has been outlined to assemble enantiomerically pure Betti bases with unprecedented structures. This involves the Zr-mediated reduction of pyrrolidin-2-ones to cyclic imines and their subsequent reaction with phenolic derivatives.
Zr-mediated synthesis of chiral cyclic imines and their application in Betti reactions
Luca Banfi;Lisa Moni;Renata Riva;Valeria Rocca;Andrea Basso
2018-01-01
Abstract
A novel synthetic strategy has been outlined to assemble enantiomerically pure Betti bases with unprecedented structures. This involves the Zr-mediated reduction of pyrrolidin-2-ones to cyclic imines and their subsequent reaction with phenolic derivatives.
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