Trichloramine is a hazardous disinfection by-product that is of particular relevance in indoor swimming pools. To better understand its fate in pool waters, apparent second order rate constants (kapp) at pH 7 for its reaction with several model compounds were determined. kapp values at pH 7 for nitrogenous compounds were found to increase in the following order: ammonia~amides (~10-2-10-1M-1s-1)
Trichloramine reactions with nitrogenous and carbonaceous compounds: Kinetics, products and chloroform formation
CANONICA, GIORGIO;
2015-01-01
Abstract
Trichloramine is a hazardous disinfection by-product that is of particular relevance in indoor swimming pools. To better understand its fate in pool waters, apparent second order rate constants (kapp) at pH 7 for its reaction with several model compounds were determined. kapp values at pH 7 for nitrogenous compounds were found to increase in the following order: ammonia~amides (~10-2-10-1M-1s-1)
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