The electrochemical removal of a synthetic solution containing 190 mg L −1 of Novacron Blue (NB) dye has been studied by electro-Fenton process using a carbon felt gas-diffusion O 2 cathode to produce in situ hydrogen peroxide by oxygen reduction. The effect of operating conditions (Fe 2 + concentration, applied current and pH solution on the efficiency of the process) was investigated. Results clearly showed that NB and their products may be effectively degraded by the •OH radicals produced by the reaction between the Fe 2 + ions and the in situ electrogenerated H 2 O 2 at carbon felt gas-diffusion O 2 cathode. After 4 h of electrolysis, chemical oxygen demand (COD) removal was only 34% when no ferrous ions were added to the solutions, while the presence of ferrous ion greatly improved COD removal to more than 90%, depending on operating conditions. Spectrophotometric analysis indicated that the discoloration of the solution occurs in all operating conditions, while gas chromatographic / mass spectrometry analysis confirmed the degradation of NB dye via identification of the principal intermediates formed.
Application of electro-Fenton process as alternative for degradation of Novacron Blue dye
PANIZZA, MARCO
2014-01-01
Abstract
The electrochemical removal of a synthetic solution containing 190 mg L −1 of Novacron Blue (NB) dye has been studied by electro-Fenton process using a carbon felt gas-diffusion O 2 cathode to produce in situ hydrogen peroxide by oxygen reduction. The effect of operating conditions (Fe 2 + concentration, applied current and pH solution on the efficiency of the process) was investigated. Results clearly showed that NB and their products may be effectively degraded by the •OH radicals produced by the reaction between the Fe 2 + ions and the in situ electrogenerated H 2 O 2 at carbon felt gas-diffusion O 2 cathode. After 4 h of electrolysis, chemical oxygen demand (COD) removal was only 34% when no ferrous ions were added to the solutions, while the presence of ferrous ion greatly improved COD removal to more than 90%, depending on operating conditions. Spectrophotometric analysis indicated that the discoloration of the solution occurs in all operating conditions, while gas chromatographic / mass spectrometry analysis confirmed the degradation of NB dye via identification of the principal intermediates formed.
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