The peculiarities in the phase formation in the Al-rich region of the Ce-Ni-Al and Sm-Ni-Al ternary systems have been investigated by means of optical and scanning electron microscopy, electron probe microanalysis and x-ray powder diffraction (XRD) study. The following ternary phases have been identified: Ce4Ni6Al23 (τ1, mS66-Y4Ni6Al23), CeNiAl4 (τ3, oS24-YNiAl4), Sm3Ni5Al19 (τ2, oS108-Gd3Ni5Al19), Sm4Ni6Al23 (τ1, mS66-Y4Ni6Al23) and SmNiAl4 (τ3, oS24-YNiAl4). Moreover, a temperature of 622 °C ± 1 has been established for the ternary eutectic reaction L ↔ (Al) + NiAl3 + αCe3Al11 using a differential scanning calorimeter (DSC). The general characteristics of the sections are discussed in comparison with those of other R-Ni-Al systems (R = rare earths).

Effect of the Rare-Earth Addition (R = Ce, Sm) on the Phase Equilibria and Microstructure of Ni-Al Alloys

DELSANTE, SIMONA;PARODI, NADIA;BORZONE, GABRIELLA
2014-01-01

Abstract

The peculiarities in the phase formation in the Al-rich region of the Ce-Ni-Al and Sm-Ni-Al ternary systems have been investigated by means of optical and scanning electron microscopy, electron probe microanalysis and x-ray powder diffraction (XRD) study. The following ternary phases have been identified: Ce4Ni6Al23 (τ1, mS66-Y4Ni6Al23), CeNiAl4 (τ3, oS24-YNiAl4), Sm3Ni5Al19 (τ2, oS108-Gd3Ni5Al19), Sm4Ni6Al23 (τ1, mS66-Y4Ni6Al23) and SmNiAl4 (τ3, oS24-YNiAl4). Moreover, a temperature of 622 °C ± 1 has been established for the ternary eutectic reaction L ↔ (Al) + NiAl3 + αCe3Al11 using a differential scanning calorimeter (DSC). The general characteristics of the sections are discussed in comparison with those of other R-Ni-Al systems (R = rare earths).
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/721976
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 3
  • ???jsp.display-item.citation.isi??? 3
social impact