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EnglishWe study the polarized Surface Enhanced Raman Scattering from randomly oriented molecules adsorbed on near-field coupled gold nanowires. We show that the scattering is polarized always along the wire-to-wire nanocavities. We find the exact angular dependence for the polarized, unpolarized, parallel- and cross-polarized SERS intensity. Finally we develop a model that fits the experimental data and allows to measure the field enhancement and the re-radiation enhancement factors, independently, and retrieve the depolarization ratio of the probe molecules.
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| Titolo: | Strongly polarized scattering in surface enhanced Raman spectroscopy of randomly distributed molecules on gold nanowires | |
| Autori: | ||
| Data di pubblicazione: | 2011 | |
| Abstract: | We study the polarized Surface Enhanced Raman Scattering from randomly oriented molecules adsorbed on near-field coupled gold nanowires. We show that the scattering is polarized always along the wire-to-wire nanocavities. We find the exact angular dependence for the polarized, unpolarized, parallel- and cross-polarized SERS intensity. Finally we develop a model that fits the experimental data and allows to measure the field enhancement and the re-radiation enhancement factors, independently, and retrieve the depolarization ratio of the probe molecules. | |
| Handle: | http://hdl.handle.net/11567/713567 | |
| Appare nelle tipologie: | 04.01 - Contributo in atti di convegno |
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