The release of repulsive interactions of steric and/or stereoelectronic nature and the onset of a new extended and effective conjugation concur to an unprecedented and synthetically appealing shift of a nitro group from the beta- to the alpha-position with respect to the aryl group of a styrene moiety.

An unprecedented “reverse” 1,2-migration of a nitro group within an α-aryl-β-nitroethenyl moiety driven by steric and stereoelectronic effects

BIANCHI, LARA;MACCAGNO, MASSIMO;PETRILLO, GIOVANNI;TAVANI, CINZIA
2007-01-01

Abstract

The release of repulsive interactions of steric and/or stereoelectronic nature and the onset of a new extended and effective conjugation concur to an unprecedented and synthetically appealing shift of a nitro group from the beta- to the alpha-position with respect to the aryl group of a styrene moiety.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/249052
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