The release of repulsive interactions of steric and/or stereoelectronic nature and the onset of a new extended and effective conjugation concur to an unprecedented and synthetically appealing shift of a nitro group from the beta- to the alpha-position with respect to the aryl group of a styrene moiety.
An unprecedented “reverse” 1,2-migration of a nitro group within an α-aryl-β-nitroethenyl moiety driven by steric and stereoelectronic effects
BIANCHI, LARA;MACCAGNO, MASSIMO;PETRILLO, GIOVANNI;TAVANI, CINZIA
2007-01-01
Abstract
The release of repulsive interactions of steric and/or stereoelectronic nature and the onset of a new extended and effective conjugation concur to an unprecedented and synthetically appealing shift of a nitro group from the beta- to the alpha-position with respect to the aryl group of a styrene moiety.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
