Experimental Validation of Electrothermal and Aging Parameter Identification for Lithium-Ion Batteries

Modeling and predicting the long-term performance of Li-ion batteries is crucial for the effective design and efficient operation of integrated energy systems. In this paper, we introduce a comprehensive semi-empirical model for Li-ion cells, capturing electrothermal and aging features. This model replicates the evolution of cell voltage, capacity, and internal resistance, in relation to the cell actual operating conditions, and estimates the ongoing degradation in capacity and internal resistance due to the battery use. Thus, the model articulates into two sub-models, an electrothermal one, describing the battery voltage, and an aging one, computing the ongoing degradation. We first propose an approach to identify the parameters of both sub-models. Then, we validate the identification procedure and the accuracy of the electrothermal and aging models through an experimental campaign, also comprising two real cycle load tests at different temperatures, in which real measurements collected from real Li-ion cells are used. The overall model demonstrates good performances in simulating battery characteristics and forecasting degradation. The results show a Mean Absolute Percentage Error (MAPE) lower than 1% for battery voltage and capacity, and a maximum absolute error on internal resistance that is on par with the most up-to-date empirical models. The proposed approach is therefore well-suited for implementation in system modeling, and can be employed as an informative tool for enhancing battery design and operational strategies.