Membrane bubble aeration unit: Experimental study of the performance in lab scale and full-scale systems

The transfer of oxygen is limited at the gas/liquid interface by the low solubility of oxygen in water. Fine bubble diffusers have a standard oxygen transfer efficiency (SOTE) lower than 30% in a full-scale system. Porous membranes can be employed as diffusor to improve the efficiencies taking the advantage of the high exchange interfacial area and the low volume of equipment. The aim of this work is to study the feasibility of membrane systems for aeration in a full-scale system. Several membrane modules were prepared using hollow fibers hydrophobic membranes and compared with the traditional disk diffusor currently employed in wastewater treatment. The mass transfer coefficient (KLa) and SOTE were assessed by carrying out the aeration tests in both lab-scale and full-scale systems exploring different operating parameters such as system flow rate, the geometry of the module and the surface of the device. The advantage and disadvantages of employing membranes in the aeration process were highlighted. The membrane unit showed better overall mass transfer efficiency increasing from 28% at the lab-scale to 34% in the full-scale system. Unlike the conventional disk diffusers, it has been found that the membrane aerator can operate with significantly lower air flow rates, which leads to a doubling of the efficiency. Moreover, the membrane surface generating the bubbles can be easily increased while maintaining the same module footprint, which in turn allowing a further increase of efficiency from 9% to 24%. However, important phenomena of scaling were observed on the membrane surface.