The tunable interconversion between two highly ordered supramolecular motifs (G-quartet K+-templated column and G-ribbon) of a lipophilic guanosine derivative fueled by cation complexation and release in a cryptand [2.2.2] containing guanosine solution is reported. The process is controlled by the sequential addition of acid and base.
REVERSIBLE INTERCONVERSION BETWEEN A SUPRAMOLECULAR POLYMER AND A DISCRETE OCTAMERIC SPECIES FROM A GUANOSINE DERIVATIVE BY DYNAMIC CATION BINDING AND RELEASE
PANDOLI, OMAR;
2006-01-01
Abstract
The tunable interconversion between two highly ordered supramolecular motifs (G-quartet K+-templated column and G-ribbon) of a lipophilic guanosine derivative fueled by cation complexation and release in a cryptand [2.2.2] containing guanosine solution is reported. The process is controlled by the sequential addition of acid and base.File in questo prodotto:
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