We demonstrated the one-pot synthesis of copper nanoparticles (mainly as Cu0; CuNPs) mediated by carboxymethylcellulose in water and their heterocatalytic activity when supported on lignocellulosic bamboo slices (CuNPs-BSs). The real-time monitoring of CuNPs formation was performed by time-domain NMR under different temperatures and concentrations of copper precursor. Several 1,4-disubstituted 1,2,3-triazoles were synthesized in organic and aqueous solution at 70 °C. The unprecedented CuNPs-BSs were reused several times with minimal leaching (1.14 ppm) of the copper nanocatalyst. Graphical Abstract: [Figure not available: see fulltext.]

One-Pot Synthesis of Carboxymethylcellulose-Templated Copper-NPs for Heterocatalytic Huisgen-Click Reactions on Lignocellulosic Bamboo Slices

Ginoble Pandoli O.
2022-01-01

Abstract

We demonstrated the one-pot synthesis of copper nanoparticles (mainly as Cu0; CuNPs) mediated by carboxymethylcellulose in water and their heterocatalytic activity when supported on lignocellulosic bamboo slices (CuNPs-BSs). The real-time monitoring of CuNPs formation was performed by time-domain NMR under different temperatures and concentrations of copper precursor. Several 1,4-disubstituted 1,2,3-triazoles were synthesized in organic and aqueous solution at 70 °C. The unprecedented CuNPs-BSs were reused several times with minimal leaching (1.14 ppm) of the copper nanocatalyst. Graphical Abstract: [Figure not available: see fulltext.]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/1074878
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