A thorough study on the (E) to (Z) photoisomerization of ferulic acid derivatives (esters, amides of all types, and ketones) was carried out. At the photostationary state, only aliphatic or benzylic tertiary amides reach a nearly complete conversion of (E) isomers into the (Z) ones, whereas for esters, primary and secondary amides or aromatic tertiary amides mixtures of (Z)/(E) ranging from 7 : 93 to 72 : 28 are observed. Ketones show rather limited photoisomerization. However, (Z) ketones may be obtained by the reaction of organometal compounds with an isomerized (Z) Weinreb amide.
Scheda prodotto non validato
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo
Titolo: | A Thorough Study on the Photoisomerization of Ferulic Acid Derivatives | |
Autori: | ||
Data di pubblicazione: | 2021 | |
Rivista: | ||
Handle: | http://hdl.handle.net/11567/1066571 | |
Appare nelle tipologie: | 01.01 - Articolo su rivista |