Solid oxide fuel cells (SOFC) are a forward-looking technology for highly efficient, environmentally–friendly power generation. SOFC single cells and stack systems are multilayer structures consisting of ceramic and metallic materials with different well defined electrical transport properties. All components have to show well-adjusted thermal expansion behaviour, chemical compatibility of material interfaces and chemical stability in the prevailing temperature and gas atmosphere. Performance and long-term stability improvements at affordable costs can be obtained by lowering the operating temperature. This goal requires drastic reduction of electrodes polarisation resistance as well as highly-conducting electrolyte materials. The use of new and nanostructured material and the application of appropriate technologies for the production of optimized microstructure becomes essential for highly efficient SOFCs operating in the medium and low temperature range. A review of state-of-art materials is given together with a perspective presentation of innovative materials and technologies for new types of SOFC.
recent developments and new perspectives in solid oxide fuel cells materials
BARBUCCI, ANTONIO;PICCARDO, PAOLO;CARPANESE, MARIA PAOLA
2006-01-01
Abstract
Solid oxide fuel cells (SOFC) are a forward-looking technology for highly efficient, environmentally–friendly power generation. SOFC single cells and stack systems are multilayer structures consisting of ceramic and metallic materials with different well defined electrical transport properties. All components have to show well-adjusted thermal expansion behaviour, chemical compatibility of material interfaces and chemical stability in the prevailing temperature and gas atmosphere. Performance and long-term stability improvements at affordable costs can be obtained by lowering the operating temperature. This goal requires drastic reduction of electrodes polarisation resistance as well as highly-conducting electrolyte materials. The use of new and nanostructured material and the application of appropriate technologies for the production of optimized microstructure becomes essential for highly efficient SOFCs operating in the medium and low temperature range. A review of state-of-art materials is given together with a perspective presentation of innovative materials and technologies for new types of SOFC.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.