Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).
From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design
Bochicchio D.;
2018-01-01
Abstract
Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).File in questo prodotto:
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Bochicchio - From Isodesmic.pdf
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11567_977500_Accepeted - From Isodesmic to Highly Cooperative.pdf
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