Carbonyl protected α-hydroxyaldehydes 3 were obtained in high diastereomeric purity through LiAlH4 reduction of corresponding β-oxosulfoxides 2 prepared via acylation of p-tolyl p-tolylthiomethyl sulfoxide 1
Asymmetric Synthesis of Protected alpha-Hydroxyaldehydes from Acyl Chlorides using p -Tolyl-p-Tolylthiomethyl Sulfoxide as Chiral Carbonyl Synthon
GUANTI, GIUSEPPE;NARISANO, ENRICA;BANFI, LUCA;
1983-01-01
Abstract
Carbonyl protected α-hydroxyaldehydes 3 were obtained in high diastereomeric purity through LiAlH4 reduction of corresponding β-oxosulfoxides 2 prepared via acylation of p-tolyl p-tolylthiomethyl sulfoxide 1
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