19 intermetallic compounds with the general formula RMX (R ≡ Ca, Sr, Ba, Eu, Yb; M ≡ Cu, Ag, Au; X ≡ Sb, Bi) were synthesized and structurally studied by X-ray methods on powders and single crystals. The ternary phases crystallize in four ordered structural types: ZrBeSi, LiGaGe, TiNiSi and MgAgAs. Some comments are given on the parameters controlling the structure of these phases, and the volume effects are calculated.

RMX compounds formed by alkaline earths, europium and ytterbium-I. Ternary phases with M ≡ Cu, Ag, Au; X ≡ Sb, Bi

MERLO, FRANCO;PANI, MARCELLA;FORNASINI, MARIA LUISA
1990-01-01

Abstract

19 intermetallic compounds with the general formula RMX (R ≡ Ca, Sr, Ba, Eu, Yb; M ≡ Cu, Ag, Au; X ≡ Sb, Bi) were synthesized and structurally studied by X-ray methods on powders and single crystals. The ternary phases crystallize in four ordered structural types: ZrBeSi, LiGaGe, TiNiSi and MgAgAs. Some comments are given on the parameters controlling the structure of these phases, and the volume effects are calculated.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/333172
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