A series of asymmetrized bis(hydroxymethyl)propanoates (BHYMP*) has been prepared in both enantiomeric forms through a chemoenzymatic methodology involving complementary diacetate monohydrolyses and diol monoacetylations catalyzed by lipases.
Chemoenzymic synthesis of asymmetrized bis(hydroxymethyl)propanoates as a new family of chiral building blocks
BANFI, LUCA;BASSO, ANDREA;GUANTI, GIUSEPPE;
1997-01-01
Abstract
A series of asymmetrized bis(hydroxymethyl)propanoates (BHYMP*) has been prepared in both enantiomeric forms through a chemoenzymatic methodology involving complementary diacetate monohydrolyses and diol monoacetylations catalyzed by lipases.
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