Nanosized titanium dioxide immobilized on silica gel was synthesized and used as fixedbed phase for V(V) pre-concentration, followed by inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. Three different sorbents were prepared by sol–gel method starting from a mixture of titanium isopropoxide, 2-propanol and water, and characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM) and BET analysis. V(V), the most stable and toxic oxidation state of the element, present in water and beverages samples, was selectively sorbed, pre-concentrated, quantitatively eluted by 0.1 M HCl and analyzed by ICP-OES. The effectiveness of the procedure was first assessed on tap water enriched with 1 lg L1 of V(V) obtaining recoveries up to 92% (n= 4). The pre-concentration step was then optimized for complex matrices such as tea infusions and red and white wines. The reliability of the procedure was assessed on the same beverages samples spiked with 20–250 lg L1. Quantitative recoveries (82– 95%, n= 4) were assured avoiding any sample pre-treatment, generally essential in such complex matrices, obtaining good precision (RSD< 12%, n= 3). The method was then applied to the determination of V(V) in commercial tea infusions and wines.

Solid-phase extraction of vanadium(V) from teainfusions and wines on immobilized nanometer titanium dioxide followed by ICP-OES analysis

Valentina Caratto;Maurizio Ferretti
2019-01-01

Abstract

Nanosized titanium dioxide immobilized on silica gel was synthesized and used as fixedbed phase for V(V) pre-concentration, followed by inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. Three different sorbents were prepared by sol–gel method starting from a mixture of titanium isopropoxide, 2-propanol and water, and characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM) and BET analysis. V(V), the most stable and toxic oxidation state of the element, present in water and beverages samples, was selectively sorbed, pre-concentrated, quantitatively eluted by 0.1 M HCl and analyzed by ICP-OES. The effectiveness of the procedure was first assessed on tap water enriched with 1 lg L1 of V(V) obtaining recoveries up to 92% (n= 4). The pre-concentration step was then optimized for complex matrices such as tea infusions and red and white wines. The reliability of the procedure was assessed on the same beverages samples spiked with 20–250 lg L1. Quantitative recoveries (82– 95%, n= 4) were assured avoiding any sample pre-treatment, generally essential in such complex matrices, obtaining good precision (RSD< 12%, n= 3). The method was then applied to the determination of V(V) in commercial tea infusions and wines.
File in questo prodotto:
File Dimensione Formato  
234 - Arabian TiO2 vanadium.pdf

accesso aperto

Tipologia: Documento in versione editoriale
Dimensione 1.05 MB
Formato Adobe PDF
1.05 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11567/1003800
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 8
  • ???jsp.display-item.citation.isi??? 5
social impact